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莨菪烷 - 版本历史
2026-04-18T04:56:10Z
本wiki的该页面的版本历史
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123.130.221.191：建立内容为“{{chembox | verifiedrevid = 444238033 | Reference =<ref>''Merck Index'', 11th Edition, '''9689'''.</ref> | ImageFileL1 = Tropane svg.svg | ImageSizeL1 = 150px | I…”的新页面
2021-07-21T16:45:33Z
<p>建立内容为“{{chembox | verifiedrevid = 444238033 | Reference =<ref>''Merck Index'', 11th Edition, '''9689'''.</ref> | ImageFileL1 = Tropane svg.svg | ImageSizeL1 = 150px | I…”的新页面</p>
<p><b>新页面</b></p><div>{{chembox<br />
| verifiedrevid = 444238033<br />
| Reference =<ref>''Merck Index'', 11th Edition, '''9689'''.</ref><br />
| ImageFileL1 = Tropane svg.svg<br />
| ImageSizeL1 = 150px<br />
| ImageFileR1 = Tropane-3D-sticks.png<br />
| ImageSizeR1 = 150px<br />
| IUPACName = ''N''-Methyl-8-azabicyclo[3.2.1]octane<br />
| OtherNames = 2,3-Dihydro-8-methylnortropidine<br />
| Section1 = {{Chembox Identifiers<br />
| Abbreviations =<br />
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}<br />
| ChemSpiderID = 553556<br />
| InChI = 1S/C8H15N/c1-9-7-3-2-4-8(9)6-5-7/h7-8H,2-6H2,1H3/t7-,8+<br />
| InChIKey = XLRPYZSEQKXZAA-OCAPTIKFBA<br />
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}<br />
| StdInChI = 1S/C8H15N/c1-9-7-3-2-4-8(9)6-5-7/h7-8H,2-6H2,1H3/t7-,8+<br />
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}<br />
| StdInChIKey = XLRPYZSEQKXZAA-OCAPTIKFSA-N<br />
| InChIKey1 = XLRPYZSEQKXZAA-OCAPTIKFSA-N<br />
| CASNo = 529-17-9<br />
| EINECS =<br />
| PubChem = 637986<br />
| SMILES = N1(C)[C@H]2CC[C@@H]1CCC2<br />
| InChI =<br />
| RTECS =<br />
| MeSHName =<br />
| ChEBI_Ref = {{ebicite|correct|EBI}}<br />
| ChEBI = 35615<br />
| KEGG_Ref = {{keggcite|correct|kegg}}<br />
| KEGG =<br />
| ATCCode_prefix =<br />
| ATCCode_suffix =<br />
| ATC_Supplemental =}}<br />
| Section2 = {{Chembox Properties<br />
| Formula = C<sub>8</sub>H<sub>15</sub>N<br />
| MolarMass = 125.211 g/mol<br />
| Appearance =<br />
| Density = 0.9259 at 15 °C<br />
| MeltingPt =<br />
| Melting_notes =<br />
| BoilingPt = 163-169 °C<br />
| Boiling_notes =<br />
| Solubility =<br />
| SolubleOther =<br />
| Solvent =<br />
| pKa =<br />
| pKb = }}<br />
| Section7 = {{Chembox Hazards<br />
| EUClass =<br />
| EUIndex =<br />
| MainHazards =<br />
| NFPA-H =<br />
| NFPA-F =<br />
| NFPA-R =<br />
| NFPA-O =<br />
| RPhrases =<br />
| SPhrases =<br />
| RSPhrases =<br />
| FlashPt =<br />
| Autoignition =<br />
| ExploLimits =<br />
| PEL = }}<br />
}}<br />
<br />
'''莨菪烷'''（{{lang-en|'''Tropane'''}}）是一种含氮[[桥环化合物|桥环]]有机化合物。它主要因一类它的名为莨菪烷[[生物碱]]的[[衍生物]]而为人们所知，而这类生物碱包括了许多药物，如[[阿托品]]和[[可卡因]]。这两种生物碱都含有莨菪烷的衍生物[[托品酮]]。莨菪烷生物碱主要存在于[[古柯]]科植物（包括古柯）与茄科植物（包括曼德拉草、[[天仙子 (植物)|天仙子]]、[[颠茄]]、[[洋金花]]、[[马铃薯]]和[[番茄]]）之中。<ref>{{cite web | title=Atropine content of plants | work=USDA, ARS, National Genetic Resources Program. Phytochemical and Ethnobotanical Databases. <nowiki>[Online Database]</nowiki> National Germplasm Resources Laboratory, Beltsville, Maryland | url=http://sun.ars-grin.gov:8080/npgspub/xsql/duke/chemdisp.xsql?chemical=ATROPINE | accessdate=July 25, 2005}}</ref><ref>{{cite web | title=Cocaine content of plants | work=USDA, ARS, National Genetic Resources Program. Phytochemical and Ethnobotanical Databases. <nowiki>[Online Database]</nowiki> National Germplasm Resources Laboratory, Beltsville, Maryland | url=http://sun.ars-grin.gov:8080/npgspub/xsql/duke/chemdisp.xsql?chemical=COCAINE | accessdate=July 25, 2005}}</ref><br />
<br />
莨菪烷[[分子]]中的氮桥在1号碳和5号碳之间；尽管莨菪烷有两个手性碳原子，但由于分子的对称性，它并没有[[光学活性]]。<br />
<br />
8-氮杂双环[3.2.1]辛烷（少了一个8位甲基的莨菪烷）被称作降莨菪烷。<br />
<br />
== 另见==<br />
* [[莨菪烷生物碱]]<br />
* [[阿托品]]<br />
* [[托品]]<br />
<br />
== 参考资料 ==<br />
<br />
{{Reflist}}<br />
<br />
==外部链接==<br />
* [http://tropane.lab-q.net/tropane-chemistry Tropane Chemistry]（英文）<br />
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[[Category:莨菪烷| ]]<br />
==参考来源==<br />
*[http://zh.wikipedia.org/wiki/%E8%8E%A8%E8%8F%AA%E7%83%B7 维基百科-莨菪烷]</div>
123.130.221.191